Redox L2


Section A: Very Short Answer Questions

  1. Define oxidation and reduction in terms of electron transfer.
  2. What is meant by a redox reaction?
  3. In the reaction:
    Zn(s) + CuSO₄(aq) → ZnSO₄(aq) + Cu(s),
    identify the species oxidised and reduced.
  4. What is a half reaction?
  5. Name the oxidising and reducing agents in:
    Cl₂(g) + 2NaBr(aq) → 2NaCl(aq) + Br₂(l)

Section B: Short Answer Questions (2 Marks Each)

  1. Write the oxidation and reduction half reactions for the following overall redox reaction:
    Fe²⁺ + Ce⁴⁺ → Fe³⁺ + Ce³⁺
  2. Identify the oxidant and reductant in the following reaction:
    H₂S(g) + Cl₂(g) → 2HCl(g) + S(s)
  3. Balance the following redox reaction using the half reaction method (in acidic medium):
    Fe²⁺ + Cr₂O₇²⁻ + H⁺ → Fe³⁺ + Cr³⁺ + H₂O
  4. Balance the following redox reaction by half reaction method in basic medium:
    MnO₄⁻ + I⁻ → MnO₂ + I₂
  5. Explain why redox reactions are always coupled reactions.

Section C: Application-Based Questions (3 Marks Each)

  1. Identify oxidation and reduction half reactions in:
    2Cu₂O + Cu₂S → 6Cu + SO₂
    Also name the oxidising and reducing agents.
  2. Balance the following redox reaction using the half reaction method in acidic medium:
    Cr₂O₇²⁻ + SO₃²⁻ → Cr³⁺ + SO₄²⁻
  3. Define the following with examples:
    a) Oxidising Agent
    b) Reducing Agent
    c) Redox Reaction
  4. Classify the following reactions as combination, decomposition, displacement or disproportionation redox reactions:
    a) Cl₂ + 2OH⁻ → Cl⁻ + ClO⁻ + H₂O
    b) 2Na + Cl₂ → 2NaCl
    c) 2KClO₃ → 2KCl + 3O₂
  5. Explain the role of electrons in balancing redox equations using the Fe²⁺ and MnO₄⁻ redox couple in acidic medium.


Section A: Very Short Answer Questions

  • Oxidation: Loss of electrons
  • Reduction: Gain of electrons

A redox reaction is a chemical reaction in which oxidation and reduction occur simultaneously.

  • Zn is oxidised: Zn → Zn²⁺ + 2e⁻
  • Cu²⁺ is reduced: Cu²⁺ + 2e⁻ → Cu

A half reaction shows either the oxidation or the reduction part of a redox process, including electron transfer.

  • Oxidising agent: Cl₂ (gets reduced)
  • Reducing agent: Br⁻ (gets oxidised)

Section B: Short Answer Questions

Oxidation half: Fe²⁺ → Fe³⁺ + e⁻
Reduction half: Ce⁴⁺ + e⁻ → Ce³⁺

  • Oxidising agent: Cl₂ (gets reduced to HCl)
  • Reducing agent: H₂S (gets oxidised to S)

Balanced (acidic):
6Fe²⁺ + Cr₂O₇²⁻ + 14H⁺ → 6Fe³⁺ + 2Cr³⁺ + 7H₂O

Balanced (basic):
2MnO₄⁻ + 3I⁻ + 2H₂O → 2MnO₂ + 3I₂ + 4OH⁻

Redox reactions involve electron transfer. Since electrons lost in oxidation must be gained in reduction, both processes occur together (coupled).


Section C: Application-Based Questions

Oxidation: S in Cu₂S → SO₂
Reduction: Cu⁺ in Cu₂O → Cu

  • Reducing agent: Cu₂S
  • Oxidising agent: Cu₂O

Balanced:
Cr₂O₇²⁻ + 3SO₃²⁻ + 8H⁺ → 2Cr³⁺ + 3SO₄²⁻ + 4H₂O

a) Oxidising Agent: Species that causes oxidation, e.g., KMnO₄
b) Reducing Agent: Species that causes reduction, e.g., Zn in Zn + Cu²⁺ → Zn²⁺ + Cu
c) Redox Reaction: Any reaction involving both oxidation and reduction

a) Disproportionation
b) Combination
c) Decomposition

Fe²⁺ → Fe³⁺ + e⁻ (oxidation)
MnO₄⁻ + 5e⁻ + 8H⁺ → Mn²⁺ + 4H₂O (reduction)
Electrons lost = electrons gained → balance redox